Electron transfer rate on mixed valence states of Class II/III transition for N, N′-diphenyl-1,4-phenylenediamine structures as a polyaniline unit

The first example of the determination of the electron transfer rate ( λ, V, Δ G *, k th) for N, N ′-diphenyl-1,4-phenylenediamine derivatives using the Marcus–Hush theory is described. These results were in good agreement with the ones obtained using variable-temperature IR spectra measurements....

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Bibliographic Details
Published in:Chemical physics letters 2003-08, Vol.378 (1), p.18-23
Main Authors: Nishiumi, Toyohiko, Nomura, Yasuhiro, Higuchi, Masayoshi, Yamamoto, Kimihisa
Format: Article
Language:English
Subjects:
Chemistry
Exact sciences and technology
General and physical chemistry
Ion-molecule, ion-ion, and charge-transfer reactions
Theory of reactions, general kinetics
Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry
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Summary:The first example of the determination of the electron transfer rate ( λ, V, Δ G *, k th) for N, N ′-diphenyl-1,4-phenylenediamine derivatives using the Marcus–Hush theory is described. These results were in good agreement with the ones obtained using variable-temperature IR spectra measurements.
ISSN:0009-2614
1873-4448
DOI:10.1016/S0009-2614(03)01237-5