Polarizability anisotropies, magnetizability anisotropies and molecular quadrupole moments of acetylene, methylacetylene and dimethylacetylene

Measurements of the Rayleigh depolarization ratios (with and without inclusion of the vibrational Raman contributions), Cotton-Mouton effects and electric field-gradient induced birefringences of gaseous HCCH, HCCCH 3 and CH 3CCCH 3 at 632.8 nm are analyzed in conjunction with other data to obtai...

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Bibliographic Details
Published in:Chemical physics letters 1997-11, Vol.279 (1), p.22-28
Main Authors: Keir, Roland I., Lamb, David W., Ritchie, Geoffrey L.D., Watson, Jonathan N.
Format: Article
Language:English
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Summary:Measurements of the Rayleigh depolarization ratios (with and without inclusion of the vibrational Raman contributions), Cotton-Mouton effects and electric field-gradient induced birefringences of gaseous HCCH, HCCCH 3 and CH 3CCCH 3 at 632.8 nm are analyzed in conjunction with other data to obtain reliable values of the polarizability anisotropies, magnetizability anisotropies and quadrupole moments of these molecules.
ISSN:0009-2614
1873-4448
DOI:10.1016/S0009-2614(97)01118-4