Imido analogues of p-block oxoanions

The synthesis of imido analogues of p-block oxoanions is a relatively new area of investigation. This review summarises synthetic routes towards such anions and gives an analysis of the structure and reactivity of complexes containing the following anions, [B(NR) 3] 3−; [C(NR) 3] 2−; [Si(NR) 4] 4−;...

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Bibliographic Details
Published in:Coordination chemistry reviews 2002-04, Vol.227 (2), p.217-232
Main Authors: Aspinall, Garreth M., Copsey, May C., Leedham, Angela P., Russell, Christopher A.
Format: Article
Language:English
Subjects:
Anions
Imido
Lithium
Main group
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Summary:The synthesis of imido analogues of p-block oxoanions is a relatively new area of investigation. This review summarises synthetic routes towards such anions and gives an analysis of the structure and reactivity of complexes containing the following anions, [B(NR) 3] 3−; [C(NR) 3] 2−; [Si(NR) 4] 4−; [P(NR) 4] 3−; [HP(NR) 3] 2−; [As(NR) 3] 3−; [Sb(NR) 3] 3−; [S(NR) 3] 2−; [Se(NR) 3] 2−; [Te(NR) 3] 2− and [S(NR) 4] 2−.
ISSN:0010-8545
1873-3840
DOI:10.1016/S0010-8545(02)00014-0