Cationic photoinitiated copolymerization of 1-propenyl–vinyl ether systems

A kinetic investigation of the photoinitiated cationic copolymerization of 1-propenyl ethers with vinyl ethers monomers was performed by using FT-IR and 1 H-NMR analysis. FT-IR results, obtained in bulk, indicate a higher reactivity of the vinyl ether with respect to the 1-propenyl ether double bond...

Full description

Saved in:
Bibliographic Details
Published in:European polymer journal 2002-04, Vol.38 (4), p.655-659
Main Authors: Sangermano, M, Malucelli, G, Bongiovanni, R, Priola, A, Annby, U, Rehnberg, N
Format: Article
Language:English
Subjects:
Applied sciences
Cationic photopolymerization
Copolymerization
Exact sciences and technology
Physicochemistry of polymers
Polymerization
Polymers and radiations
Propenyl ether
Vinyl ether
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:A kinetic investigation of the photoinitiated cationic copolymerization of 1-propenyl ethers with vinyl ethers monomers was performed by using FT-IR and 1 H-NMR analysis. FT-IR results, obtained in bulk, indicate a higher reactivity of the vinyl ether with respect to the 1-propenyl ether double bond. 1 H-NMR analysis, in CDCl 3 solution, confirms these results which agree with the literature data concerning monofunctional systems. The properties of the UV cured copolymerization products are investigated by DMTA analysis and discussed on the basis of the kinetic investigation results.
ISSN:0014-3057
1873-1945
DOI:10.1016/S0014-3057(01)00220-8