Structures of Mn(II) thiocyanate co-ordination polymers from flexible bipyridyl ligands

Crystallisation of flexible bipyridyl ligands with MnCl 2·4H 2O and KSCN gives co-ordination polymers of composition [Mn(NCS) 2(H 2O) 2(Py 2C 2H 4)](Py 2C 2H 4) 2(H 2O) 2 ( 1) (Py 2C 2H 4=1,2-bis(4-pyridyl)ethane), [Mn 2(NCS) 4(Py 2C 3H 6) 4] n ( 2) (Py 2C 3H 6=1,3-bis(4-pyridyl)propane) and [Mn(NCS...

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Bibliographic Details
Published in:Inorganica Chimica Acta 2001-06, Vol.318 (1), p.175-180
Main Authors: Plater, M.John, Foreman, Mark R.St J., Howie, R.A., Skakle, Janet M.S.
Format: Article
Language:English
Subjects:
Coordination polymer complexes
Crystal structures
Manganese complexes
Thiocyanate complexes
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Summary:Crystallisation of flexible bipyridyl ligands with MnCl 2·4H 2O and KSCN gives co-ordination polymers of composition [Mn(NCS) 2(H 2O) 2(Py 2C 2H 4)](Py 2C 2H 4) 2(H 2O) 2 ( 1) (Py 2C 2H 4=1,2-bis(4-pyridyl)ethane), [Mn 2(NCS) 4(Py 2C 3H 6) 4] n ( 2) (Py 2C 3H 6=1,3-bis(4-pyridyl)propane) and [Mn(NCS) 2(CH 3CH 2OH) 2(Py 2C 6H 12)] n ( 3) (Py 2C 6H 12=1,6-bis(4-pyridyl)hexane). The structures were solved by single crystal structure determinations.
ISSN:0020-1693
1873-3255
DOI:10.1016/S0020-1693(01)00398-X