Extended materials based on the [Mo 6Cl 8] 4+ building block bridged by 4,4′-bipyridine

Octahedral molybdenum clusters containing labile SO 3CF 3 − ligands attached to the vertices of the octahedron were allowed to react with the linear bidentate 4,4′-bipyridine to produce microporous xerogels that exhibit size selective ion exchange. The octahedral metal cluster [Mo 6Cl 8(OsO 2CF 3) 6...

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Bibliographic Details
Published in:Inorganica Chimica Acta 2001-12, Vol.325 (1), p.171-174
Main Authors: Bain, R.L, Shriver, D.F, Ellis, Donald E
Format: Article
Language:English
Subjects:
Bipyridine
Microporous xerogels
Molybdenum clusters
SO 3CF 3 − ligands
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Summary:Octahedral molybdenum clusters containing labile SO 3CF 3 − ligands attached to the vertices of the octahedron were allowed to react with the linear bidentate 4,4′-bipyridine to produce microporous xerogels that exhibit size selective ion exchange. The octahedral metal cluster [Mo 6Cl 8(OsO 2CF 3) 6] 2− reacts with 4,4′-bipyridene to form a jell which was dried to form an amorphous solid composed of Mo 6Cl 8 clusters linked by 4,4′-bipyridene.
ISSN:0020-1693
1873-3255
DOI:10.1016/S0020-1693(01)00631-4