Synthesis and characterization of several lumazine derivative complexes of Co(II), Ni(II), Cu(II), Cd(II), Pd(II) and Pt(II). X-ray structures of a mononuclear copper complex and a dinuclear cadmium complex

• Published in: Inorganica Chimica Acta 2003-07, Vol.351, p.356-362
• Main Authors: Acuña-Cueva, Esther R., Faure, René, Illán-Cabeza, Nuria A., Jiménez-Pulido, Sonia B., Moreno-Carretero, Miguel N., Quirós-Olozábal, Miguel
• Format: Article
• Language: English
• Subjects: Complexes; Crystal structures; Lumazine; Pteridine
• ISSN: 0020-1693; 1873-3255
• DOI: 10.1016/S0020-1693(03)00172-5

The synthesis of the new Co(II), Ni(II), Cu(II), Cd(II), Pd(II) and Pt(II) complexes with 1-methyllumazine (1-methylpteridine-2,4(1 H,3 H)-dione, MLM) and 1,6,7-trymethyllumazine (1,6,7-trimethylpteridine-2,4(1 H,3 H)-dione, MLMD) is described. The coordination chemistry of these ligands have been investigated and an usual bidentate bonding mode through the N5 and O4 atoms is observed. These complexes present the form M IICl 2L and were characterized by elemental analyses, TG and DSC, as well as by IR, UV–Vis, EPR spectroscopy and magnetic measurements. The crystal structures of [CuCl 2(MLMD)(H 2O)] and [CdCl 2(MLM)(H 2O)] 2 have been determined by X-ray diffraction methods. The copper(II) compound exists in the monomeric form with an environment around the metal ion as a distorted square-based pyramidal geometry whereas the cadmium complex was observed as dimers with an edge-sharing distorted octahedral coordination sphere around each cadmium center. Complexes with 1-methyllumazine (MLM) and 1,6,7-trymethyllumazine (MLMD) are described. A bidentate co-ordinate-bonding mode through the N5 and O4 atoms is observed. The structures of [CuCl 2(MLMD)(H 2O)] and [CdCl 2(MLM)(H 2O)] 2 have been XRD determined. The copper(II) compound exists in the monomeric form with a distorted square-based pyramidal geometry; the cadmium complex was observed as dimers with an edge-sharing distorted octahedral co-ordination sphere around cadmium.