Dipyridylamine-ligated octamolybdate clusters aggregated into extended ribbons and layers via hydrogen bonding

The hydrothermal reaction of MoO3 with 4,4′-dipyridylamine yields [Mo8O26(4,4′-dpa)2][4,4′-dpaH2]2. The structure consists of octamolybdate clusters linked via H-bonding to the (dpaH2)2+ cations into one-dimensional ribbons which are in turn connected through H-bonding into two-dimensional sheets....

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Bibliographic Details
Published in:Inorganica Chimica Acta 1999-09, Vol.292 (1), p.131-136
Main Authors: LaDuca, Robert L, Rarig, Randy S, Zapf, Pamela J, Zubieta, Jon
Format: Article
Language:English
Subjects:
Cluster complexes
Crystal structures
Dipyridylamine complexes
Molybdate complexes
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Summary:The hydrothermal reaction of MoO3 with 4,4′-dipyridylamine yields [Mo8O26(4,4′-dpa)2][4,4′-dpaH2]2. The structure consists of octamolybdate clusters linked via H-bonding to the (dpaH2)2+ cations into one-dimensional ribbons which are in turn connected through H-bonding into two-dimensional sheets.
ISSN:0020-1693
1873-3255
DOI:10.1016/S0020-1693(99)00176-0