Thermodynamic criterion for the identification of sulphur-containing compounds by gas chromatography

A thermodynamic criterion, Δ Q, is proposed which permits reliable identification of the functional groups of aliphatic compounds by gas chromatographic analysis on stationary phases of different polarities. The advantages of such a criterion in those cases where the method based on Δ I values fails...

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Bibliographic Details
Published in:Journal of Chromatography A 1984-01, Vol.290, p.275-287
Main Authors: Golovnya, R.V., Grigoryeva, D.N.
Format: Article
Language:English
Subjects:
Analytical chemistry
Chemistry
Chromatographic methods and physical methods associated with chromatography
Exact sciences and technology
Gas chromatographic methods
Other chromatographic methods
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Summary:A thermodynamic criterion, Δ Q, is proposed which permits reliable identification of the functional groups of aliphatic compounds by gas chromatographic analysis on stationary phases of different polarities. The advantages of such a criterion in those cases where the method based on Δ I values fails are demonstrated.
ISSN:0021-9673
DOI:10.1016/S0021-9673(01)93582-4