Application of gas chromatographic headspace analysis to the determination of ionization constants of organic bases in complex mixtures

The possibility of using gas chromatographic headspace analysis in the determination of ionization constants of organic bases in complex mixtures in considered. A method for the determination of the ionization constant of an organic base which is represented in the chromatogram as an unresolved peak...

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Bibliographic Details
Published in:Journal of Chromatography A 1979-04, Vol.171, p.49-54
Main Authors: Vitenberg, A.G., Dimitrova, Z.St, Ioffe, B.V.
Format: Article
Language:English
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Summary:The possibility of using gas chromatographic headspace analysis in the determination of ionization constants of organic bases in complex mixtures in considered. A method for the determination of the ionization constant of an organic base which is represented in the chromatogram as an unresolved peak together with a neutral compound is proposed and the limits of its applicability are discussed.
ISSN:0021-9673
DOI:10.1016/S0021-9673(01)95284-7