A method for calculating capacity factors at different mobile phase compositions and at different temperatures for members of homologous series in reversed-phase high-performance liquid chromatography. III

The linear dependences of log k′ on the carbon chain length, on log(methanol concentration) and on the reciprocal of absolute temperature in reversed-phase high-performance liquid chromatography of homologous series have been used as a basis for deriving equations for calculating the capacity factor...

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Bibliographic Details
Published in:Journal of Chromatography A 1984, Vol.299 (1), p.109-117
Main Author: Dufek, P.
Format: Article
Language:English
Subjects:
Analytical chemistry
Chemistry
Chromatographic methods and physical methods associated with chromatography
Exact sciences and technology
Other chromatographic methods
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Summary:The linear dependences of log k′ on the carbon chain length, on log(methanol concentration) and on the reciprocal of absolute temperature in reversed-phase high-performance liquid chromatography of homologous series have been used as a basis for deriving equations for calculating the capacity factors of any member of a homologous series at any mobile phase composition and at any temperature. Good agreement was observed between the published and re-calculated data.
ISSN:0021-9673
DOI:10.1016/S0021-9673(01)97825-2