A fresh approach to voltammetric modelling

A modular semianalytic procedure, alternative to simulation, is described for predicting the transient current response to any applied potential signal under a wide variety of voltammetric conditions. Diverse geometries may be treated; the electrode reaction may have any degree of reversibility; hom...

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Bibliographic Details
Published in:Journal of electroanalytical chemistry (Lausanne, Switzerland) Switzerland), 2002-11, Vol.537 (1), p.1-5
Main Authors: Mahon, Peter J, Myland, Jan C, Oldham, Keith B
Format: Article
Language:English
Subjects:
Chemistry
Convolution
Electrochemistry
Exact sciences and technology
General and physical chemistry
Kinetics and mechanism of reactions
Modelling
Voltammetry
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Summary:A modular semianalytic procedure, alternative to simulation, is described for predicting the transient current response to any applied potential signal under a wide variety of voltammetric conditions. Diverse geometries may be treated; the electrode reaction may have any degree of reversibility; homogeneous chemical reactions may be involved. Conceptually, the method consists of splitting the overall problem into three components, each of which is solved separately. Examples presented include cyclic voltammetry and (Osteryoung) square-wave voltammetry.
ISSN:1572-6657
1873-2569
DOI:10.1016/S0022-0728(02)01263-9