Studies on sulfinatodehalogenation: the addition reaction of halocarbons with olefins initiated by sodium dithionite

Halocarbons such as carbon tetrachloride, CCl 3Br, CF 3CCl 3, BrCF 2CF 2Br, BrCF 2CFClBr and CF 2Br 2, reacted with olefins in the presence of the sulfinatodehalogenation reagent sodium dithionite under mild conditions to give the corresponding adducts. In the case of F113, CFCl 2CF 2CFCl 2 and CF 3...

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Bibliographic Details
Published in:Journal of fluorine chemistry 2001, Vol.110 (1), p.59-61
Main Authors: Wu, Fan-Hong, Huang, Wei-Yuan
Format: Article
Language:English
Subjects:
Addition reaction
Halocarbons
Sodium dithionite
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Summary:Halocarbons such as carbon tetrachloride, CCl 3Br, CF 3CCl 3, BrCF 2CF 2Br, BrCF 2CFClBr and CF 2Br 2, reacted with olefins in the presence of the sulfinatodehalogenation reagent sodium dithionite under mild conditions to give the corresponding adducts. In the case of F113, CFCl 2CF 2CFCl 2 and CF 3Cl 3, the polyfluoroalkylation product resulted.
ISSN:0022-1139
1873-3328
DOI:10.1016/S0022-1139(01)00400-6