Electrochemical fluorination of trialkylphosphines

The electrochemical fluorination (ECF) of trialkylphosphines results in the formation of the corresponding tris(perfluoroalkyl)difluorophosphoranes in good yield. In the case of ECF of tri( iso-butyl)phosphine, isomerisation of iso- into n-alkyl compound occurs.

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Bibliographic Details
Published in:Journal of fluorine chemistry 2000-04, Vol.103 (1), p.57-61
Main Authors: Ignat’ev, Nikolai, Sartori, Peter
Format: Article
Language:English
Subjects:
Electrochemical fluorination
Simons process
Trialkylphosphines
Tris(perfluoroalkyl)difluorophosphoranes
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Description
Summary:The electrochemical fluorination (ECF) of trialkylphosphines results in the formation of the corresponding tris(perfluoroalkyl)difluorophosphoranes in good yield. In the case of ECF of tri( iso-butyl)phosphine, isomerisation of iso- into n-alkyl compound occurs.
ISSN:0022-1139
1873-3328
DOI:10.1016/S0022-1139(99)00253-5