CdTe quantum dots by melt heat treatment in borosilicate glasses

• Published in: Journal of non-crystalline solids 1997-10, Vol.219, p.205-211
• Main Authors: Barbosa, L.C., Reynoso, V.C.S., de Paula, A.M., de Oliveira, C.R.M., Alves, O.L., Craievich, A.F., Marotti, R.E., Brito Cruz, C.H., Cesar, C.L.
• Format: Article
• Language: English
• ISSN: 0022-3093; 1873-4812
• DOI: 10.1016/S0022-3093(97)00330-X

CdTe quantum dots in borosilicate glasses were produced and their growth kinetics, the effects of quantum confinement for electrons and phonons and the time resolved optical transmission were studied. Quantum dots in the range of 10 to 25 Å with a 5% size dispersion were grown. The growth kinetics were studied by small angle X-ray scattering using synchrotron light. A spherical k · p model for the electron confinement explains absorption data and selection rules, and a dielectric continuum model for the phonon confinement could explain the resonant longitudinal and surface optical phonons, as well as their overtone combinations. The time response of absorption was studied by a pump—probe measurement on the femtosecond time scale. For samples showing a large amount of surface traps the recovery time can be as fast as 300 fs, while for an almost surface trap free sample it remains on the 1–3 ps time scale.