The crystal structure of 5-hydro- and 7-hydro- s-indacenide-Rh(COD). A comparison with similar complexes

The monometallic complex with Rh(COD) of 5-hydro and 7-hydro- s-indacenide has been synthesized and structurally characterized. It crystallizes in the triclinic space group P 1 ̄ with a=12.513(2), b=15.902(2), c=8.423(1) Å, α=97.0(1), β=91.4(1), γ=111.7(1)°. The geometry of the ligand was revealed t...

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Bibliographic Details
Published in:Journal of organometallic chemistry 2000-04, Vol.601 (2), p.267-270
Main Authors: Ceccon, Alberto, Ganis, Paolo, Manoli, Francesco, Venzo, Alfonso
Format: Article
Language:English
Subjects:
Crystal structure
Hyperconjugative effects
Indacenide complexes
Rhodium complexes
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Summary:The monometallic complex with Rh(COD) of 5-hydro and 7-hydro- s-indacenide has been synthesized and structurally characterized. It crystallizes in the triclinic space group P 1 ̄ with a=12.513(2), b=15.902(2), c=8.423(1) Å, α=97.0(1), β=91.4(1), γ=111.7(1)°. The geometry of the ligand was revealed to be substantially different from that of its 2,6-dimethylated homologues. An explanation for this behaviour is given in terms of electronic and mesomeric effects.
ISSN:0022-328X
1872-8561
DOI:10.1016/S0022-328X(00)00078-4