A novel synthesis of 1,1′-unsymmetrical disubstituted heteroarylferrocene

Stepwise Stille coupling reaction of 1,1′-bis(tributylstannyl)ferrocene with different heterocyclic bromides was achieved in the presence of Pd-complex catalyst via two steps to afford unsymmetrical 1,1′-disubstituted heteroarylferrocene compounds.

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Bibliographic Details
Published in:Journal of organometallic chemistry 2000-10, Vol.612 (1), p.172-175
Main Authors: Liu, Chao-Min, Guo, Yin-Long, Wu, Xiao-li, Liang, Yong-min, Ma, Yong-Xiang
Format: Article
Language:English
Subjects:
1,1′-bis(Tributylstannyl)ferrocene
1,1′-Unsymmetrical diheteroaryl-ferrocene
Stille reaction
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Description
Summary:Stepwise Stille coupling reaction of 1,1′-bis(tributylstannyl)ferrocene with different heterocyclic bromides was achieved in the presence of Pd-complex catalyst via two steps to afford unsymmetrical 1,1′-disubstituted heteroarylferrocene compounds.
ISSN:0022-328X
1872-8561
DOI:10.1016/S0022-328X(00)00496-4