Rhodium and palladium complexes from 1,1′ and 1,2 ferrocenylphosphine as bidentate ligands. Versatile coordination

The complexation of the mixed bidentate ligands 1-diphenylphosphino-1′-diphenylthiophosphinoferrocenyl and 1,2-bis(diphenylphosphino)ferrocenyl with rhodium(I) and palladium(II) species yield a range of mono- and dirhodium or palladium complexes. Their interest as possible catalysts for alkene hydro...

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Bibliographic Details
Published in:Journal of organometallic chemistry 2000-10, Vol.613 (1), p.77-85
Main Authors: Broussier, Roland, Bentabet, Emmanuelle, Laly, Myriam, Richard, Philippe, Kuz'mina, Lyudmila G, Serp, Philippe, Wheatley, Nigel, Kalck, Philippe, Gautheron, Bernard
Format: Article
Language:English
Subjects:
Catalysis
Ferrocene
Palladium
Phosphine
Rhodium
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Summary:The complexation of the mixed bidentate ligands 1-diphenylphosphino-1′-diphenylthiophosphinoferrocenyl and 1,2-bis(diphenylphosphino)ferrocenyl with rhodium(I) and palladium(II) species yield a range of mono- and dirhodium or palladium complexes. Their interest as possible catalysts for alkene hydroformylation and alkoxycarbonylation and Heck coupling reactions has been assessed. Fe[C 5Me 4P(S)Ph 2][C 5Me 4PPh 2]PdCl 2 and Fe[C 5H 2-1,2-(PPh 2) 2-4- t Bu][C 5H 5]PdCl 2 have been characterized by single-crystal X-ray diffraction studies.
ISSN:0022-328X
1872-8561
DOI:10.1016/S0022-328X(00)00501-5