Synthesis of adenosine containing carborane modification

The carboranyl cage is a new modifying entity for nucleosides and DNA-oligonucleotides. Most of carborane–nucleoside conjugates described so far belong to pyrimidine series. Herein, the first synthesis of adenosine, nucleoside containing purine nucleic base, modified with carborane cluster, is descr...

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Bibliographic Details
Published in:Journal of organometallic chemistry 2003-08, Vol.680 (1), p.124-126
Main Authors: Olejniczak, Agnieszka B, Semenuk, Andrey, Kwiatkowski, Marek, Lesnikowski, Zbigniew J
Format: Article
Language:English
Subjects:
Antiviral
BNCT
Boron
Carborane
Nucleosides
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Summary:The carboranyl cage is a new modifying entity for nucleosides and DNA-oligonucleotides. Most of carborane–nucleoside conjugates described so far belong to pyrimidine series. Herein, the first synthesis of adenosine, nucleoside containing purine nucleic base, modified with carborane cluster, is described. The carboranyl cage is a new modifying entity for nucleosides and DNA-oligonucleotides. Most of carborane–nucleoside conjugates described so far belong to pyrimidine series. Herein, the first synthesis of adenosine, nucleoside containing purine nucleic base, modified with carborane cluster, is described.
ISSN:0022-328X
1872-8561
DOI:10.1016/S0022-328X(03)00217-1