Experimental evidence at atomic resolution of intra- and intermolecular CO⋯π(arene) bond interactions

The crystal data of a number of carbonyl compounds have been reinvestigated. Interactions between carbonyl groups and π-arene systems have been more deeply discussed from a stereochemical point of view revealing the presence of stabilizing interactions. Preliminar ab initio calculations are in agree...

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Bibliographic Details
Published in:Journal of organometallic chemistry 1999-06, Vol.583 (1), p.126-130
Main Authors: Gambaro, Alessandro, Ganis, Paolo, Manoli, Francesco, Polimeno, Antonino, Santi, Saverio, Venzo, Alfonso
Format: Article
Language:English
Subjects:
Ab initio calculations
Conformational analysis
Tricarbonylchromium complexes
Unconventional bond interactions
X-ray features
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Summary:The crystal data of a number of carbonyl compounds have been reinvestigated. Interactions between carbonyl groups and π-arene systems have been more deeply discussed from a stereochemical point of view revealing the presence of stabilizing interactions. Preliminar ab initio calculations are in agreement with this interpretation.
ISSN:0022-328X
1872-8561
DOI:10.1016/S0022-328X(99)00120-5