Controlled radical polymerization initiated by stable radical terminated polytetrahydrofuran

Block copolymers of tetrahydrofuran and styrene were prepared by using stable free radical polymerization (SFRP) of styrene with 2,2,6,6-tetramethyl-1-piperidinyl-1-oxy (TEMPO) terminated polytetrahydrofuran (PTHF). For this purpose azo containing PTHFs were prepared and reacted with TEMPO.

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Bibliographic Details
Published in:Polymer (Guilford) 1997-05, Vol.38 (11), p.2861-2863
Main Authors: YAGCI, Y, AYSEGÜL BASKAN DÜZ, ÖNEN, A
Format: Article
Language:English
Subjects:
Applied sciences
cationic polymerization
Exact sciences and technology
Organic polymers
Physicochemistry of polymers
Polymerization
Preparation, kinetics, thermodynamics, mechanism and catalysts
stable free radical polymerization
TEMPO
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Description
Summary:Block copolymers of tetrahydrofuran and styrene were prepared by using stable free radical polymerization (SFRP) of styrene with 2,2,6,6-tetramethyl-1-piperidinyl-1-oxy (TEMPO) terminated polytetrahydrofuran (PTHF). For this purpose azo containing PTHFs were prepared and reacted with TEMPO.
ISSN:0032-3861
1873-2291
DOI:10.1016/S0032-3861(97)85626-1