Synthesis of higher-carbon sugars by addition of organometallic reagents to aldehydes or lactols derived from carbohydrates

The addition of different Grignard or lithium organometallic reagents to lactols ( 1, 6, 21) or aldehydes ( 10), derived from d-glucose or d-mannose, to give the new higher-carbon sugars ( 2, 3, 7– 9, 13– 19, 22 and 23) is reported. Graphic

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Bibliographic Details
Published in:Tetrahedron 2001-05, Vol.57 (22), p.4729-4739
Main Authors: Marco-Contelles, José, de Opazo, Elsa, Arroyo, Nieves
Format: Article
Language:English
Subjects:
higher-carbon sugars
organometallic reagent
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Description
Summary:The addition of different Grignard or lithium organometallic reagents to lactols ( 1, 6, 21) or aldehydes ( 10), derived from d-glucose or d-mannose, to give the new higher-carbon sugars ( 2, 3, 7– 9, 13– 19, 22 and 23) is reported. Graphic
ISSN:0040-4020
1464-5416
DOI:10.1016/S0040-4020(01)00410-0