The chemistry of pentavalent organobismuth reagents. Part 14. Recent advances in the copper-catalyzed phenylation of amines

A reinvestigation of the copper-mediated phenylation of amines by Biv reagents is reported. The influence of the ligands bound to bismuth and the basicity of the amines have been examined. These results, combined with our previous observations, led to the development of a new system for the quantita...

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Published in:Tetrahedron 1997-03, Vol.53 (12), p.4137-4144
Main Authors: Arnauld, Thomas, Barton, Derek H.R., Doris, Eric
Format: Article
Language:English
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Summary:A reinvestigation of the copper-mediated phenylation of amines by Biv reagents is reported. The influence of the ligands bound to bismuth and the basicity of the amines have been examined. These results, combined with our previous observations, led to the development of a new system for the quantitative phenylation of selected hindered aliphatic and aromatic amines. A reinvestigation of the copper-mediated phenylation of amines by Biv reagents is reported. This led to the development of a new system for the quantitative phenylation of selected hindered aliphatic and aromatic amines.
ISSN:0040-4020
1464-5416
DOI:10.1016/S0040-4020(97)00133-6