Attempted stereocontrol at C-2′ of strigol-type compounds by a Michael reaction/elimination approach

By a Michael addition / nucleophilic substitution / elimination sequence the stereocontrol at C-2′ in strigol-typed compounds is in principle possible. However, the method is unsuitable for practical application since it has been shown that a stereolabile intermediate is involved. Graphic

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Bibliographic Details
Published in:Tetrahedron 1998-04, Vol.54 (14), p.3413-3438
Main Authors: Röhrig, Susanne, Hennig, Lothar, Findeisen, Matthias, Welzel, Peter, Frischmuth, Katja, Marx, Andreas, Petrowitsch, Tanja, Koll, Peter, Müller, Dietrich, Mayer-Figge, Heike, Sheldrick, William S.
Format: Article
Language:English
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Summary:By a Michael addition / nucleophilic substitution / elimination sequence the stereocontrol at C-2′ in strigol-typed compounds is in principle possible. However, the method is unsuitable for practical application since it has been shown that a stereolabile intermediate is involved. Graphic
ISSN:0040-4020
1464-5416
DOI:10.1016/S0040-4020(98)00076-3