DiTOX-mediated synthesis of 2-bromo-4-deoxypyranoside derivatives

Stereocontrolled cycloaddition of Danishefsky's diene to syn-2-formyl-2-methyl-1,3-dithiane 1-oxide is used as the basis for a short stereoselective synthesis of a 2-bromo-4-deoxymannose derivative. Stereocontrolled cycloaddition of Danishefsky's diene to syn-2-formyl-2-methyl-1,3-dithlane...

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Bibliographic Details
Published in:Tetrahedron 1998-11, Vol.54 (48), p.14573-14580
Main Authors: Page, Philip C Bulman, McKenzie, Michael J, Buckle, Derek R
Format: Article
Language:English
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Summary:Stereocontrolled cycloaddition of Danishefsky's diene to syn-2-formyl-2-methyl-1,3-dithiane 1-oxide is used as the basis for a short stereoselective synthesis of a 2-bromo-4-deoxymannose derivative. Stereocontrolled cycloaddition of Danishefsky's diene to syn-2-formyl-2-methyl-1,3-dithlane 1-oxide is used as the basis for a short stereoselective synthesis of a 2-bromo-4-deoxymannose derivative.
ISSN:0040-4020
1464-5416
DOI:10.1016/S0040-4020(98)00916-8