Solution-phase ring opening cross-metathesis of bicyclic alkenes with styrene derivatives and its application to “resin capture” solid-phase synthesis

The solution-phase ring opening cross-metathesis (ROM) of bicyclic alkenes with styrene derivatives is described. The influence of bicyclic alkene substituents on the rate and product distribution of solution-phase ROM reactions with styrene derivatives is discussed. In addition, a method for the “r...

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Bibliographic Details
Published in:Tetrahedron 1999-07, Vol.55 (27), p.8169-8178
Main Authors: Cuny, Gregory D., Cao, Jingrong, Sidhu, Alban, Hauske, James R.
Format: Article
Language:English
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Summary:The solution-phase ring opening cross-metathesis (ROM) of bicyclic alkenes with styrene derivatives is described. The influence of bicyclic alkene substituents on the rate and product distribution of solution-phase ROM reactions with styrene derivatives is discussed. In addition, a method for the “resin capture” of solution-phase ROM products by resin-bound amines is also illustrated. A method for the “resin capture” of solution-phase ROM products by resin-bound amines is described.
ISSN:0040-4020
1464-5416
DOI:10.1016/S0040-4020(99)00298-7