Chloroalkylation of aryl aldehydes using alkylboron dichlorides in the presence of oxygen

Reactions of aryl aldehydes with alkylboron dichlorides in the presence of oxygen at room temperature produces arylalkyl chlorides in good to excellent yields. Reactions of aryl aldehydes with alkylboron dichloride derivatives in the presence of oxygen at room temperature produces arylalkyl chloride...

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Bibliographic Details
Published in:Tetrahedron letters 2001-09, Vol.42 (36), p.6239-6241
Main Authors: Kabalka, George W, Wu, Zhongzhi, Ju, Yuhong
Format: Article
Language:English
Subjects:
aldehydes
alkyl halides
alkylation
boron and compounds
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Summary:Reactions of aryl aldehydes with alkylboron dichlorides in the presence of oxygen at room temperature produces arylalkyl chlorides in good to excellent yields. Reactions of aryl aldehydes with alkylboron dichloride derivatives in the presence of oxygen at room temperature produces arylalkyl chlorides in good to excellent yields.
ISSN:0040-4039
1873-3581
DOI:10.1016/S0040-4039(01)01271-0