A new carbohydrate-based synthetic approach to trichothecenes. Synthesis of a bicyclic BC core of verrucarol from d-galactose

An advanced bicyclic BC intermediate towards the total synthesis of verrucarol has been prepared from d-galactose via an intramolecular aldehyde–allylstannane reaction. An advanced bicyclic BC intermediate towards the total synthesis of verrucarol has been prepared from d-galactose via an intramolec...

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Bibliographic Details
Published in:Tetrahedron letters 2001-09, Vol.42 (38), p.6679-6682
Main Author: Ermolenko, Mikhail S
Format: Article
Language:English
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Summary:An advanced bicyclic BC intermediate towards the total synthesis of verrucarol has been prepared from d-galactose via an intramolecular aldehyde–allylstannane reaction. An advanced bicyclic BC intermediate towards the total synthesis of verrucarol has been prepared from d-galactose via an intramolecular aldehyde–allylstannane reaction.
ISSN:0040-4039
1873-3581
DOI:10.1016/S0040-4039(01)01366-1