Synthesis of arylhalonium compounds [including (4-methylphenyl) phenylfluoronium] by the nuclear–chemical method

The nuclear–chemical method has been used for the synthesis of previously unknown multivalent fluorine derivatives, namely (4-methylphenyl)phenylfluoronium. The synthesis includes the ion-molecular reaction of free phenyl cations generated by tritium β-decay with 4-methylhalobenzenes. The influence...

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Bibliographic Details
Published in:Tetrahedron letters 2002-05, Vol.43 (22), p.4123-4124
Main Authors: Shchepina, N.E, Badun, G.A, Nefedov, V.D, Toropova, M.A, Fedoseev, V.M, Avrorin, V.V, Lewis, Scott B
Format: Article
Language:English
Subjects:
halogen compounds
labeling
phenyl cations
radiation chemistry
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Summary:The nuclear–chemical method has been used for the synthesis of previously unknown multivalent fluorine derivatives, namely (4-methylphenyl)phenylfluoronium. The synthesis includes the ion-molecular reaction of free phenyl cations generated by tritium β-decay with 4-methylhalobenzenes. The influence of the halogen atom (F, Cl, Br, I) as well as effects of the methyl substituent on the yields of the corresponding halonium compounds have been investigated. Graphic
ISSN:0040-4039
1873-3581
DOI:10.1016/S0040-4039(02)00717-7