Allylic and benzylic oxidation using cobalt(II) alkyl phosphonate modified silica

The allylic and benzylic oxidation of a range of substrates proceeds in good yield using catalytic quantities of cobalt(II) alkyl phosphonate modified silica and tert-butyl hydroperoxide. The allylic and benzylic oxidation of a range of substrates proceeds in good yield using catalytic quantities of...

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Bibliographic Details
Published in:Tetrahedron letters 2003-05, Vol.44 (22), p.4283-4286
Main Authors: Jurado-Gonzalez, Magdalena, Sullivan, Alice C., Wilson, John R.H.
Format: Article
Language:English
Subjects:
benzylic
cobalt
immobilised reagents
oxidation
phosphonate
silica
steroids
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Summary:The allylic and benzylic oxidation of a range of substrates proceeds in good yield using catalytic quantities of cobalt(II) alkyl phosphonate modified silica and tert-butyl hydroperoxide. The allylic and benzylic oxidation of a range of substrates proceeds in good yield using catalytic quantities of cobalt(II) alkyl phosphonate modified silica and tert-butyl hydroperoxide.
ISSN:0040-4039
1873-3581
DOI:10.1016/S0040-4039(03)00833-5