A facile synthesis of 1,2-oxaphospholenes and stereoselective conversion into oxaphospholanes

Treatment of α-acylallylphosphonates with m-CPBA in the presence of MgSO 4, afforded 1,2-oxaphosphol-3-enes 2-oxides and the subsequent cuprate addition produced 1,2-oxaphospholanes stereoselectively. Graphic

Saved in:
Bibliographic Details
Published in:Tetrahedron letters 2003-07, Vol.44 (31), p.5811-5814
Main Authors: Hah, Jung Hwan, Lee, Bum Sung, Lee, Shi Yong, Lee, Hee-Yoon
Format: Article
Language:English
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:Treatment of α-acylallylphosphonates with m-CPBA in the presence of MgSO 4, afforded 1,2-oxaphosphol-3-enes 2-oxides and the subsequent cuprate addition produced 1,2-oxaphospholanes stereoselectively. Graphic
ISSN:0040-4039
1873-3581
DOI:10.1016/S0040-4039(03)01395-9