Accelerated benzylation reaction utilizing dibenzyl carbonate as an alkylating reagent

Ionic liquids can effectively accelerate slow N-benzylation reactions utilizing dibenzyl carbonate as an alkylating reagent. By applying microwave irradiation in the presence of the same ionic liquid, additional rate enhancement was accomplished. Graphic

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Bibliographic Details
Published in:Tetrahedron letters 2003-09, Vol.44 (36), p.6943-6945
Main Authors: Shieh, Wen-Chung, Lozanov, Mario, Repič, Oljan
Format: Article
Language:English
Subjects:
DABCO
dibenzyl carbonate
ionic liquid
microwave-assisted reactions
N-benzylation
nucleophilic catalyst
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Description
Summary:Ionic liquids can effectively accelerate slow N-benzylation reactions utilizing dibenzyl carbonate as an alkylating reagent. By applying microwave irradiation in the presence of the same ionic liquid, additional rate enhancement was accomplished. Graphic
ISSN:0040-4039
1873-3581
DOI:10.1016/S0040-4039(03)01711-8