Synthesis of a new spiroacetal based herbicide

[3R ∗, 5S ∗, 6S ∗]-3-Benzyloxy-5-methoxy-1,7-dioxaspiro[5.5]undecane 3 and [3R ∗, 5S ∗, 6S ∗]-3-methoxy-5-benzyloxy-1,7-dioxaspiro[5.5]undecane 4 were prepared making use of a base induced rearrangement of a 4,5-epoxy-1,7-dioxaspiro[5.5]undecane. The synthesis of a new spiroacetal based herbicide is...

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Bibliographic Details
Published in:Tetrahedron letters 1997-01, Vol.38 (20), p.3591-3594
Main Authors: Brimble, Margaret A., Johnston, Andrew D., Furneaux, Richard H.
Format: Article
Language:English
Subjects:
agrochemicals
pesticides
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Summary:[3R ∗, 5S ∗, 6S ∗]-3-Benzyloxy-5-methoxy-1,7-dioxaspiro[5.5]undecane 3 and [3R ∗, 5S ∗, 6S ∗]-3-methoxy-5-benzyloxy-1,7-dioxaspiro[5.5]undecane 4 were prepared making use of a base induced rearrangement of a 4,5-epoxy-1,7-dioxaspiro[5.5]undecane. The synthesis of a new spiroacetal based herbicide is reported making use of a base induced rearrangement of an epoxyspiroacetal.
ISSN:0040-4039
1873-3581
DOI:10.1016/S0040-4039(97)00671-0