Transition metal complexes in organic synthesis, part 38. First total synthesis of carbazomycin G and H

The first total synthesis of the carbazole quinol alkaloids carbazomycin G and H has been achieved by a highly convergent synthesis using an iron-mediated construction of the carbazole nucleus as key-step. The first total synthesis of the carbazole quinol alkaloids carbazomycin G and H is described...

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Bibliographic Details
Published in:Tetrahedron letters 1997-06, Vol.38 (23), p.4051-4054
Main Authors: Knölker, Hans-Joachim, Fröhner, Wolfgang
Format: Article
Language:English
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Summary:The first total synthesis of the carbazole quinol alkaloids carbazomycin G and H has been achieved by a highly convergent synthesis using an iron-mediated construction of the carbazole nucleus as key-step. The first total synthesis of the carbazole quinol alkaloids carbazomycin G and H is described by a convergent iron-mediated construction of the carbazole nucleus starting with the complexes 1a, 1b, and the arylamine 2 as precursors.
ISSN:0040-4039
1873-3581
DOI:10.1016/S0040-4039(97)00826-5