Ring opening cross-metathesis on solid support

Ring opening cross-metathesis (ROM) of bicyclic alkenes with terminal aryl alkenes on solid support was accomplished. A select group of resin-bound bicyclic alkenes underwent highly regioselective ROM with electron rich styrenes. The influence of both electronic and steric factors on regioselectivit...

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Bibliographic Details
Published in:Tetrahedron letters 1997-07, Vol.38 (30), p.5237-5240
Main Authors: Cuny, Gregory D., Cao, Jingrong, Hauske, James R.
Format: Article
Language:English
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Summary:Ring opening cross-metathesis (ROM) of bicyclic alkenes with terminal aryl alkenes on solid support was accomplished. A select group of resin-bound bicyclic alkenes underwent highly regioselective ROM with electron rich styrenes. The influence of both electronic and steric factors on regioselectivity was examined. Regioselective ring opening cross-metathesis (ROM) of resin-bound bicyclic alkenes with electron rich terminal aryl olefins.
ISSN:0040-4039
1873-3581
DOI:10.1016/S0040-4039(97)01144-1