An exceptionally reactive phosphotriester

The 1,8-naphthyl phosphotriester ( 2) is 1–2 orders of magnitude more reactive than the “standard” model phosphotriester ( 1) in phosphorolytic reactions with commonly employed nucleophilic phosphorolytic “decontamination” reagents. The 1,8-naphthyl phosphotriester ( 1) is 1–2 orders of magnitude mo...

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Bibliographic Details
Published in:Tetrahedron letters 1998-01, Vol.39 (5), p.347-350
Main Authors: Moss, Robert A., Bose, Susmita, Ragunathan, Kaliappa G., Jayasuriya, Nilu, Emge, Thomas J.
Format: Article
Language:English
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Summary:The 1,8-naphthyl phosphotriester ( 2) is 1–2 orders of magnitude more reactive than the “standard” model phosphotriester ( 1) in phosphorolytic reactions with commonly employed nucleophilic phosphorolytic “decontamination” reagents. The 1,8-naphthyl phosphotriester ( 1) is 1–2 orders of magnitude more reactive than the “standard” model phosphotriester ( 2) in phosphorolytic reactions with various nucleophiles.
ISSN:0040-4039
1873-3581
DOI:10.1016/S0040-4039(97)10517-2