First synthesis of anomeric sulfimides - efficient glycosyl donors

Sugar-derived anomeric sulfimides were prepared in high yields form the corresponding thioglycosides and their ability to act as glycosyl donors was investigated. Anomeric sulfimides have been easily obtained from the corresponding ethyl thioglycosides with high yields and good stereoselectivity on...

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Bibliographic Details
Published in:Tetrahedron letters 1998-10, Vol.39 (44), p.8097-8100
Main Authors: Cassel, Stéphanie, Plessis, Isabelle, Wessel, Hans Peter, Rollin, Patrick
Format: Article
Language:English
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Summary:Sugar-derived anomeric sulfimides were prepared in high yields form the corresponding thioglycosides and their ability to act as glycosyl donors was investigated. Anomeric sulfimides have been easily obtained from the corresponding ethyl thioglycosides with high yields and good stereoselectivity on the sulfur atom. Their ability to act as glycosyl donors has been investigated.
ISSN:0040-4039
1873-3581
DOI:10.1016/S0040-4039(98)01837-1