1,3-Dithiane polymers for the supported synthesis of ketones

The synthesis of polymeric reagents containing an odourless propane-1,3-dithiol functionality is reported. Their usefulness for the solid phase synthesis of ketones via the umpoled alkylation of 1,3-dithianes is demonstrated. Synthesis of P6 and its use for supported synthesis of ketones is reported...

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Bibliographic Details
Published in:Tetrahedron letters 1998-12, Vol.39 (50), p.9263-9266
Main Authors: Bertini, Vincenzo, Lucchesini, Francesco, Pocci, Marco, De Munno, Angela
Format: Article
Language:English
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Summary:The synthesis of polymeric reagents containing an odourless propane-1,3-dithiol functionality is reported. Their usefulness for the solid phase synthesis of ketones via the umpoled alkylation of 1,3-dithianes is demonstrated. Synthesis of P6 and its use for supported synthesis of ketones is reported.
ISSN:0040-4039
1873-3581
DOI:10.1016/S0040-4039(98)02081-4