A Mitsunobu-based procedure for the preparation of alkyl and hindered aryl isocyanates from primary amines and carbon dioxide under mild conditions

A Mitsunobu-based procedure for the preparation of alkyl and hindered aryl isocyanates in excellent yields from primary amines and carbon dioxide under very mild conditions is described. Alkyl and hindered aryl isocyanates can be prepared from primary amines and carbon dioxide using Mitsunobu techno...

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Bibliographic Details
Published in:Tetrahedron letters 1999-01, Vol.40 (2), p.363-366
Main Authors: Horvath, Michael J, Saylik, Dilek, Elmes, Patricia S., Jackson, W.R., Lovel, Craig G., Moody, Keith
Format: Article
Language:English
Subjects:
Amines
Carbon dioxide
Isocyanates
Mitsunobu reactions
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Summary:A Mitsunobu-based procedure for the preparation of alkyl and hindered aryl isocyanates in excellent yields from primary amines and carbon dioxide under very mild conditions is described. Alkyl and hindered aryl isocyanates can be prepared from primary amines and carbon dioxide using Mitsunobu technology in excellent yields under very mild conditions [Display omitted]
ISSN:0040-4039
1873-3581
DOI:10.1016/S0040-4039(98)02312-0