absolute stereochemistry of the ester functions of fumonisin B1

Synthesis of an optically active gamma-lactone related to tricarballylic acid (TCA) and correlation of this to the same lactone derived from the two sidechain TCA esters at C-14 and C-15 of fumonisin B1 has established that these esters have the R configuration.

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Bibliographic Details
Published in:Tetrahedron letters 1999-06, Vol.40 (24), p.4515-4518
Main Authors: Edwards, O.E, Blackwell, B.A, Driega, A.B, Bensimon, C, ApSimon, J.W
Format: Article
Language:English
Subjects:
chemical structure
fumonisins
nuclear magnetic resonance spectroscopy
stereochemistry
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Summary:Synthesis of an optically active gamma-lactone related to tricarballylic acid (TCA) and correlation of this to the same lactone derived from the two sidechain TCA esters at C-14 and C-15 of fumonisin B1 has established that these esters have the R configuration.
ISSN:0040-4039
1873-3581
DOI:10.1016/S0040-4039(99)00824-2