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A novel stereoselective route to a fumagillin and ovalicin synthetic intermediate

A strategy using a highly stereoselective Claisen-Ireland rearrangement followed by a Grubbs metathesis afforded in a good overall yield after further functionalisation a potentially synthetic precursor of fumagillin and ovalicin. Graphic

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Bibliographic Details
Published in:Tetrahedron letters 1999-06, Vol.40 (26), p.4797-4800
Main Authors: Picoul, Willy, Urchegui, Raquel, Haudrechy, Arnaud, Langlois, Yves
Format: Article
Language:English
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Summary:A strategy using a highly stereoselective Claisen-Ireland rearrangement followed by a Grubbs metathesis afforded in a good overall yield after further functionalisation a potentially synthetic precursor of fumagillin and ovalicin. Graphic
ISSN:0040-4039
1873-3581
DOI:10.1016/S0040-4039(99)00912-0