Photochemical oxyfluoroalkylation of styrenes by the addition of perfluoroalkyl radicals in an atmosphere of oxygen

The photochemical reaction of perfluoroalkyl iodide with α-methylstyrene and related compounds in the presence of hexabutylditin under oxygen atmosphere produces the fluoroalkylated alcohols in good yields. The reaction was photochemically initiated, and proceeded via a radical chain mediated by the...

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Bibliographic Details
Published in:Tetrahedron letters 1999-07, Vol.40 (31), p.5731-5734
Main Authors: Yoshida, Masato, Ohkoshi, Masanori, Aoki, Nobuyuki, Ohnuma, Yuki, Iyoda, Masahiko
Format: Article
Language:English
Subjects:
fluoroalkyl radical
hexabutylditin
organofluorine compounds
oxyfluoroalkylation
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Summary:The photochemical reaction of perfluoroalkyl iodide with α-methylstyrene and related compounds in the presence of hexabutylditin under oxygen atmosphere produces the fluoroalkylated alcohols in good yields. The reaction was photochemically initiated, and proceeded via a radical chain mediated by the ditin. Graphic
ISSN:0040-4039
1873-3581
DOI:10.1016/S0040-4039(99)01086-2