Synthesis of tetrahydrofurans by the reaction of α,β-epoxy alcohol derivatives with allylsilanes

In the presence of SnCl 4, α,β-epoxy alcohol derivatives easily reacted with allylsilanes to give the corresponding tetrahydrofurans in moderate yields. In the presence of SnCl 4, α,β-epoxy alcohol derivatives easily reacted with allylsilanes to give the corresponding tetrahydrofurans in moderate yi...

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Bibliographic Details
Published in:Tetrahedron letters 1999-08, Vol.40 (32), p.5877-5880
Main Authors: Sugita, Yoshiaki, Kimura, Yoko, Yokoe, Ichiro
Format: Article
Language:English
Subjects:
cycloadditions
epoxides
Sakurai-Hosomi reaction
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Summary:In the presence of SnCl 4, α,β-epoxy alcohol derivatives easily reacted with allylsilanes to give the corresponding tetrahydrofurans in moderate yields. In the presence of SnCl 4, α,β-epoxy alcohol derivatives easily reacted with allylsilanes to give the corresponding tetrahydrofurans in moderate yields. [Display omitted]
ISSN:0040-4039
1873-3581
DOI:10.1016/S0040-4039(99)01089-8