Thermokinetic investigation of the reaction of acetyl chloride with different alcohol types — Part II

The ethanolysis of acetyl chloride has been compared to the methanolysis and the hydrolysis, as well as to the reaction with n-propanol, n-butanol and n-pentanol in acetone and in toluene, to reveal chain-length effects. Pentanol, heptanol and nonanol have been included as well in the investigation,...

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Bibliographic Details
Published in:Thermochimica acta 2000-12, Vol.364 (1), p.47-58
Main Authors: Willms, T, Anderson, H.L, Heldt, K, Hinz, B
Format: Article
Language:English
Subjects:
Acetyl chloride
Alcoholysis
Benzyl alcohol
Butanol
Chemistry
Cyclohexyl methanol
Exact sciences and technology
Kinetics
Kinetics and mechanisms
n-Heptanol
Organic chemistry
Propanol
Reaction enthalpies
Reactivity and mechanisms
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Summary:The ethanolysis of acetyl chloride has been compared to the methanolysis and the hydrolysis, as well as to the reaction with n-propanol, n-butanol and n-pentanol in acetone and in toluene, to reveal chain-length effects. Pentanol, heptanol and nonanol have been included as well in the investigation, but at lower concentrations. Structural influences on the alcoholysis of acetyl chloride have been studied with the isomeric C 3 and C 4-alcohols in acetone and in toluene. Furthermore, alcoholysis of acetyl chloride with some C 7-alcohols and the reaction of benzoyl chloride with different types of alcohols have been investigated.
ISSN:0040-6031
1872-762X
DOI:10.1016/S0040-6031(00)00705-X