Thermal and spectroscopic characterization of Mg(II) complexes of nitro-substituted benzoic acids

• Published in: Thermochimica acta 2003-06, Vol.402 (1), p.45-55
• Main Authors: Srinivasan, B.R., Sawant, Sarvesh C.
• Format: Article
• Language: English
• Subjects: Chemistry; Coordination compounds; DSC; DTA; Exact sciences and technology; Inorganic chemistry and origins of life; Mg(II) complexes; Nitro-substituted benzoic acid; Preparations and properties; Reversible hydration
• ISSN: 0040-6031; 1872-762X
• DOI: 10.1016/S0040-6031(02)00533-6

The Mg(II) complexes of the nitro-substituted benzoic acids have been investigated by thermal and spectroscopic methods. Thermogravimetry (TG), differential thermal analysis (DTA), differential scanning calorimetry (DSC), and other spectroscopic methods have been used to investigate the thermal behavior and structure of the compounds [Mg(H 2O) 6](4-nba) 2·2H 2O 1 , [Mg(H 2O) 6](3-nba) 2·2H 2O 2 , [Mg(H 2O) 6](2-nba) 2·2H 2O 3 (4-nba= para-nitrobenzoate; 3-nba= meta-nitrobenzoate; and 2-nba= ortho-nitrobenzoate). All the complexes are formulated as consisting of the octahedral [Mg(H 2O) 6] 2+ cation with the carboxylates outside the coordination sphere, which is consistent with the IR, UV-Vis and 1 H NMR data. Thermal decompositions of these carboxylates are multi-stage processes. The composition of the complexes and the solid-state intermediates and the resultant products of thermolysis have been identified by IR, elemental analysis and complexometric titration. A possible scheme for the decomposition of the complexes is suggested. Heating the compounds first results in the loss of water molecules. This is followed by the loss of the nitrobenzoate resulting in the formation of oxide. Complex 1 can be reversibly hydrated. The final product of the thermal decomposition in all the cases is MgO.