Synthesis and characterization of novel hydride compounds

Novel inorganic alkali and alkaline earth hydrides of the formula MHX and MHMX wherein M is the metal, X is a singly negatively charged anion, and H comprises a novel high binding energy hydride ion were synthesized in a high temperature gas cell by reaction of atomic hydrogen with a catalyst and MX...

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Bibliographic Details
Published in:International journal of hydrogen energy 2001, Vol.26 (4), p.339-367
Main Authors: L. Mills, Randell, Dhandapani, Bala, Nansteel, Mark, He, Jiliang, Shannon, Tina, Echezuria, Alex
Format: Article
Language:English
Subjects:
Applied sciences
Direct energy conversion and energy accumulation
Electrical engineering. Electrical power engineering
Electrical power engineering
Electrochemical conversion: primary and secondary batteries, fuel cells
Exact sciences and technology
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Summary:Novel inorganic alkali and alkaline earth hydrides of the formula MHX and MHMX wherein M is the metal, X is a singly negatively charged anion, and H comprises a novel high binding energy hydride ion were synthesized in a high temperature gas cell by reaction of atomic hydrogen with a catalyst and MX or MX 2 corresponding to an alkali metal or alkaline earth metal compound, respectively. Novel hydride compounds were identified by time of flight secondary ion mass spectroscopy, X-ray photoelectron spectroscopy, proton nuclear magnetic resonance spectroscopy, and thermal decomposition with analysis by gas chromatography, and mass spectroscopy.
ISSN:0360-3199
1879-3487
DOI:10.1016/S0360-3199(00)00113-0