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Intramolecular coupling study of the resonances in the four-wave mixing signal

The effect of the intramolecular coupling on the resonances associated to the Four-wave mixing signal is studied in the present contribution. The transition and permanent dipole moments are critical quantities for this analysis of the local macroscopic polarization in the adiabatic representation wh...

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Bibliographic Details
Published in:Physics letters. A 2000-03, Vol.267 (1), p.18-23
Main Authors: Cusati, T., Paz, J.L., Salazar, M.C., Hernández, A.J.
Format: Article
Language:English
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Summary:The effect of the intramolecular coupling on the resonances associated to the Four-wave mixing signal is studied in the present contribution. The transition and permanent dipole moments are critical quantities for this analysis of the local macroscopic polarization in the adiabatic representation when the rotating wave approximation is not considered. New characteristics of the resonance, emerging as a consequence of the vibronic coupling, are studied here in the framework of a local homogeneous-linewidth third-order perturbation model.
ISSN:0375-9601
1873-2429
DOI:10.1016/S0375-9601(00)00082-7