Spectral studies of highly conducting organic composites (BEDO-TTF) x/iodine

Infrared and Raman spectral properties of the organic composites obtained by direct solid–solid charge-transfer (CT) reaction between bis(ethylenedioxy)tetrathiafulvalene (BEDO-TTF) and iodine are investigated for the first time. The band attribution, an evaluation of the average charge on the donor...

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Bibliographic Details
Published in:Synthetic metals 2001-12, Vol.125 (3), p.319-324
Main Authors: Graja, Andrzej, Świetlik, Roman, Połomska, Maria, Brau, André, Farges, Jean-Pierre
Format: Article
Language:English
Subjects:
Charge-transfer reaction in solid state
Electronic and vibrational spectra
Infrared and Raman spectroscopy
Organic conductors
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Summary:Infrared and Raman spectral properties of the organic composites obtained by direct solid–solid charge-transfer (CT) reaction between bis(ethylenedioxy)tetrathiafulvalene (BEDO-TTF) and iodine are investigated for the first time. The band attribution, an evaluation of the average charge on the donor molecule, changes of the BEDO-TTF spectra after composite formation and an analysis of the plasma-edge-like dispersion are presented and discussed.
ISSN:0379-6779
1879-3290
DOI:10.1016/S0379-6779(01)00399-X