The electrochemical behavior of (C 70) 2- p- tert-butylcalix[6]arene complex film

The electrochemical behavior of (C 70) 2- p- tert-butylcalix[6]arene inclusion complex films on a glassy carbon (GC) electrode was studied by cyclic voltammetry. Three reduction peaks and two reoxidation peaks were detected in acetonitrile (MeCN), while two pairs of reduction/reoxidation peaks were...

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Bibliographic Details
Published in:Synthetic metals 1999-12, Vol.107 (3), p.175-181
Main Authors: Liu, Ting, Li, Meixian, Li, Nanqiang, Shi, Zujin, Gu, Zhennan, Zhou, Xihuang
Format: Article
Language:English
Subjects:
(C 70) 2- p- tert-butylcalixarene
Chemistry
Cyclic voltammetry
Electrochemistry
Electrodes: preparations and properties
Exact sciences and technology
General and physical chemistry
Other electrodes
Supramolecular complex
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Summary:The electrochemical behavior of (C 70) 2- p- tert-butylcalix[6]arene inclusion complex films on a glassy carbon (GC) electrode was studied by cyclic voltammetry. Three reduction peaks and two reoxidation peaks were detected in acetonitrile (MeCN), while two pairs of reduction/reoxidation peaks were obtained in a mixed solution of MeCN and water (1:1, v/v) containing tetra-butylammonium perchlorate as the supporting electrolyte. Compared to the reduction of a pure C 70 film, the first cathodic peak potential of complex film had a positive shift both in MeCN as well as in a mixed solution of MeCN and water (1:1, v/v).
ISSN:0379-6779
1879-3290
DOI:10.1016/S0379-6779(99)00162-9