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Structural relaxation in amorphous Ni-Ti alloys prepared by mechanical alloying

Structural changes in amorphous states during prolonged milling after the completion of amorphization have been investigated through the crystallization behaviors with Ni-Ti alloys of compositions corresponding to the intermetallic compounds. In 33Ni-67Ti, the crystallization to NiTi 2 takes place i...

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Bibliographic Details
Published in:Materials science & engineering. A, Structural materials : properties, microstructure and processing Structural materials : properties, microstructure and processing, 1997-06, Vol.226, p.312-316
Main Authors: Makifuchi, Y., Terunuma, Y., Nagumo, M.
Format: Article
Language:English
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Summary:Structural changes in amorphous states during prolonged milling after the completion of amorphization have been investigated through the crystallization behaviors with Ni-Ti alloys of compositions corresponding to the intermetallic compounds. In 33Ni-67Ti, the crystallization to NiTi 2 takes place in two steps, a higher crystallization temperature dominating after prolonged milling. In 50Ni-50Ti, structural relaxation leading to the crystallization to NiTi 2 and Ni 3Ti takes place. In 30Ni-70Ti, which is close to the border of the amorphization range, the initially formed amorphous phase turns into a supersaturated solid solution of Ti in Ni.
ISSN:0921-5093
1873-4936
DOI:10.1016/S0921-5093(96)10636-5